Page 16 - Demo
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Hastelloy N alloy and other nickel-based superalloys [30] and [64] have shown an excellent resistance to corrosion [65] and compatibility with fluoride salts [66]. Hastelloy-N was deteriorating in its properties due to the intragranular attack by tellurium [67] and [68]. Since the molten salt has a high melting temperature, and if any leakage occurs, molten salt freezes without releasing radioactive material [69] and [70].
The other materials we examine for the transmutator wall include a diamond. Diamond possesses a set of properties that could withstand extreme environments, for instance: very high thermal conductivity, radiation hardness, wide bandgap and therefore an electrical insulator, high electric breakdown field, chemical inertness and resistance, transparency to the electromagnetic radiation from IR to UV [71]. Diamond also has low neutron damage or DPA (displacement per atom) [72] and [73]. Diamond has been developed as a highly efficient and robust neutron detector at the JET tokamak [74], [75].
We propose for the transmutator’s liquid medium a FLiBe molten salt where the TRUs are dissolved. FLiBe is a liquid and is a molten chemical compound of acid and alkali at high temperatures [76]. We consider this as our candidate liquid solvent, medium for a thermal transfer and a fuel processing medium.
Advantages of FLiBe molten salt and MSR based transmutator:
Transparent liquid
Real-time monitoring with laser and gamma
Green’s function impulse response sensors
Large fission cross section for fusion or fast neutrons shown in Fig. 6.
Does not react with water or air
Remains liquid up to 1400 C giving safety margins